"Tsuji-Trost reaction" meaning in English

{
  "etymology_text": "Pioneered by Jiro Tsuji in 1965 and later adapted by Barry Trost in 1973 with the introduction of phosphine ligands.",
  "forms": [
    {
      "form": "Tsuji-Trost reactions",
      "tags": [
        "plural"
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  ],
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      "expansion": "Tsuji-Trost reaction (plural Tsuji-Trost reactions)",
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  ],
  "lang": "English",
  "lang_code": "en",
  "pos": "noun",
  "senses": [
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          "langcode": "en",
          "name": "Chemistry",
          "orig": "en:Chemistry",
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      ],
      "glosses": [
        "A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product."
      ],
      "id": "en-Tsuji-Trost_reaction-en-noun-31aLYa5~",
      "links": [
        [
          "chemistry",
          "chemistry"
        ],
        [
          "palladium",
          "palladium"
        ],
        [
          "substitution reaction",
          "substitution reaction"
        ],
        [
          "substrate",
          "substrate"
        ],
        [
          "leaving group",
          "leaving group"
        ],
        [
          "allylic",
          "allylic"
        ]
      ],
      "raw_glosses": [
        "(chemistry) A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product."
      ],
      "topics": [
        "chemistry",
        "natural-sciences",
        "physical-sciences"
      ],
      "wikipedia": [
        "Tsuji-Trost reaction"
      ]
    }
  ],
  "word": "Tsuji-Trost reaction"
}

{
  "etymology_text": "Pioneered by Jiro Tsuji in 1965 and later adapted by Barry Trost in 1973 with the introduction of phosphine ligands.",
  "forms": [
    {
      "form": "Tsuji-Trost reactions",
      "tags": [
        "plural"
      ]
    }
  ],
  "head_templates": [
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  "lang": "English",
  "lang_code": "en",
  "pos": "noun",
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        "en:Chemistry"
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      "glosses": [
        "A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product."
      ],
      "links": [
        [
          "chemistry",
          "chemistry"
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        [
          "palladium",
          "palladium"
        ],
        [
          "substitution reaction",
          "substitution reaction"
        ],
        [
          "substrate",
          "substrate"
        ],
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          "leaving group",
          "leaving group"
        ],
        [
          "allylic",
          "allylic"
        ]
      ],
      "raw_glosses": [
        "(chemistry) A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product."
      ],
      "topics": [
        "chemistry",
        "natural-sciences",
        "physical-sciences"
      ],
      "wikipedia": [
        "Tsuji-Trost reaction"
      ]
    }
  ],
  "word": "Tsuji-Trost reaction"
}