See Tsuji-Trost reaction on Wiktionary
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{ "etymology_text": "Pioneered by Jiro Tsuji in 1965 and later adapted by Barry Trost in 1973 with the introduction of phosphine ligands.", "forms": [ { "form": "Tsuji-Trost reactions", "tags": [ "plural" ] } ], "head_templates": [ { "args": { "head": "Tsuji-Trost reaction" }, "expansion": "Tsuji-Trost reaction (plural Tsuji-Trost reactions)", "name": "en-noun" } ], "lang": "English", "lang_code": "en", "pos": "noun", "senses": [ { "categories": [ "English countable nouns", "English entries with incorrect language header", "English eponyms", "English lemmas", "English multiword terms", "English nouns", "Pages with 1 entry", "Pages with entries", "en:Chemistry" ], "glosses": [ "A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product." ], "links": [ [ "chemistry", "chemistry" ], [ "palladium", "palladium" ], [ "substitution reaction", "substitution reaction" ], [ "substrate", "substrate" ], [ "leaving group", "leaving group" ], [ "allylic", "allylic" ] ], "raw_glosses": [ "(chemistry) A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product." ], "topics": [ "chemistry", "natural-sciences", "physical-sciences" ], "wikipedia": [ "Tsuji-Trost reaction" ] } ], "word": "Tsuji-Trost reaction" }
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