"alkoxycyclization" meaning in English

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        "3": "alkoxy",
        "4": "cyclization",
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      "expansion": "Etymology tree\nAkkadian 𒎎𒋆𒁉𒍣𒁕 (guḫlum)bor.\nAramaic כוחלא (kuḥlā)bor.\nArabic كُحْل (kuḥl)\nAndalusian Arabic اَلْكُحُول (al-kuḥūl)bor.\nMedieval Latin alcoholder.\nMiddle English alcofol\nEnglish alcohol\nEnglish alk-\nProto-Indo-European *h₂eḱ-der.?\nAncient Greek ὀξύς (oxús)\nProto-Indo-European *ǵenh₁-\nProto-Indo-European *-os\nProto-Indo-European *ǵénh₁os\nProto-Hellenic *génos\nAncient Greek γένος (génos)\nFrench oxygènebor.\nEnglish oxygen\nEnglish -oxy\nEnglish alkoxy\nProto-Indo-European *kʷel-\nProto-Indo-European *kʷékʷlos\nAncient Greek κῠ́κλος (kŭ́klos)der.\nLate Latin cyclusbor.\nMiddle English cicle\nEnglish cycle\nProto-Indo-European *-id-\nProto-Indo-European *-yéti\nProto-Indo-European *-idyéti\nProto-Hellenic *-íďďō\nAncient Greek -ῐ́ζω (-ĭ́zō)bor.\nLate Latin -izōder.\nMiddle French -iserbor.\nMiddle English -isen\nEnglish -ize\nEnglish cyclize\nProto-Indo-European *-tisder.\nProto-Italic *-tjō\nLatin -tiō\nLatin -ātiōlbor.\nOld French -ationbor.\nMiddle English -acioun\nEnglish -ation\nEnglish cyclization\nEnglish alkoxycyclization\nFrom alkoxy + cyclization.",
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  "etymology_text": "Etymology tree\nAkkadian 𒎎𒋆𒁉𒍣𒁕 (guḫlum)bor.\nAramaic כוחלא (kuḥlā)bor.\nArabic كُحْل (kuḥl)\nAndalusian Arabic اَلْكُحُول (al-kuḥūl)bor.\nMedieval Latin alcoholder.\nMiddle English alcofol\nEnglish alcohol\nEnglish alk-\nProto-Indo-European *h₂eḱ-der.?\nAncient Greek ὀξύς (oxús)\nProto-Indo-European *ǵenh₁-\nProto-Indo-European *-os\nProto-Indo-European *ǵénh₁os\nProto-Hellenic *génos\nAncient Greek γένος (génos)\nFrench oxygènebor.\nEnglish oxygen\nEnglish -oxy\nEnglish alkoxy\nProto-Indo-European *kʷel-\nProto-Indo-European *kʷékʷlos\nAncient Greek κῠ́κλος (kŭ́klos)der.\nLate Latin cyclusbor.\nMiddle English cicle\nEnglish cycle\nProto-Indo-European *-id-\nProto-Indo-European *-yéti\nProto-Indo-European *-idyéti\nProto-Hellenic *-íďďō\nAncient Greek -ῐ́ζω (-ĭ́zō)bor.\nLate Latin -izōder.\nMiddle French -iserbor.\nMiddle English -isen\nEnglish -ize\nEnglish cyclize\nProto-Indo-European *-tisder.\nProto-Italic *-tjō\nLatin -tiō\nLatin -ātiōlbor.\nOld French -ationbor.\nMiddle English -acioun\nEnglish -ation\nEnglish cyclization\nEnglish alkoxycyclization\nFrom alkoxy + cyclization.",
  "forms": [
    {
      "form": "alkoxycyclizations",
      "tags": [
        "plural"
      ]
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      "expansion": "alkoxycyclization (plural alkoxycyclizations)",
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  "lang": "English",
  "lang_code": "en",
  "pos": "noun",
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          "name": "Chemical reactions",
          "orig": "en:Chemical reactions",
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              503
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          "ref": "2015 June 10, Ruth Dorel, Antonio M. Echavarren, “Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates”, in The Journal of Organic Chemistry, volume 80, →DOI:",
          "text": "A transition state similar to TS 34 – 33 has been proposed in the reaction of cyclopropyl gold(I) carbenes generated by retro-Buchner reaction of 7-cyclopropyl 1,3,5-cycloheptatrienes. 79 Gold(I) complexes are able to catalyze the addition of amines, alcohols, or water to 1, n -enynes affording products of amino-, alkoxy-, or hydroxycyclization under much milder conditions than other metal catalysts. 26, 32, 33, 62, 80 − 82 These additions are stereospecific, as illustrated by the alkoxycyclization of diastereomeric enynes 1m and 1h, and proceed via opening of cyclopropyl gold(I) carbene intermediates 35 by attack of the nucleophile to the cyclopropane ring (Scheme 11 ).",
          "type": "quotation"
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      "glosses": [
        "A reaction in which the addition of an alkoxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
      ],
      "id": "en-alkoxycyclization-en-noun-in7Ol7-C",
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          "alkoxy"
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          "double",
          "double bond"
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          "triple bond"
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          "cyclization"
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      "raw_glosses": [
        "(organic chemistry) A reaction in which the addition of an alkoxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
      ],
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        "chemistry",
        "natural-sciences",
        "organic-chemistry",
        "physical-sciences"
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    }
  ],
  "word": "alkoxycyclization"
}

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      "expansion": "Etymology tree\nAkkadian 𒎎𒋆𒁉𒍣𒁕 (guḫlum)bor.\nAramaic כוחלא (kuḥlā)bor.\nArabic كُحْل (kuḥl)\nAndalusian Arabic اَلْكُحُول (al-kuḥūl)bor.\nMedieval Latin alcoholder.\nMiddle English alcofol\nEnglish alcohol\nEnglish alk-\nProto-Indo-European *h₂eḱ-der.?\nAncient Greek ὀξύς (oxús)\nProto-Indo-European *ǵenh₁-\nProto-Indo-European *-os\nProto-Indo-European *ǵénh₁os\nProto-Hellenic *génos\nAncient Greek γένος (génos)\nFrench oxygènebor.\nEnglish oxygen\nEnglish -oxy\nEnglish alkoxy\nProto-Indo-European *kʷel-\nProto-Indo-European *kʷékʷlos\nAncient Greek κῠ́κλος (kŭ́klos)der.\nLate Latin cyclusbor.\nMiddle English cicle\nEnglish cycle\nProto-Indo-European *-id-\nProto-Indo-European *-yéti\nProto-Indo-European *-idyéti\nProto-Hellenic *-íďďō\nAncient Greek -ῐ́ζω (-ĭ́zō)bor.\nLate Latin -izōder.\nMiddle French -iserbor.\nMiddle English -isen\nEnglish -ize\nEnglish cyclize\nProto-Indo-European *-tisder.\nProto-Italic *-tjō\nLatin -tiō\nLatin -ātiōlbor.\nOld French -ationbor.\nMiddle English -acioun\nEnglish -ation\nEnglish cyclization\nEnglish alkoxycyclization\nFrom alkoxy + cyclization.",
      "name": "etymon"
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  "etymology_text": "Etymology tree\nAkkadian 𒎎𒋆𒁉𒍣𒁕 (guḫlum)bor.\nAramaic כוחלא (kuḥlā)bor.\nArabic كُحْل (kuḥl)\nAndalusian Arabic اَلْكُحُول (al-kuḥūl)bor.\nMedieval Latin alcoholder.\nMiddle English alcofol\nEnglish alcohol\nEnglish alk-\nProto-Indo-European *h₂eḱ-der.?\nAncient Greek ὀξύς (oxús)\nProto-Indo-European *ǵenh₁-\nProto-Indo-European *-os\nProto-Indo-European *ǵénh₁os\nProto-Hellenic *génos\nAncient Greek γένος (génos)\nFrench oxygènebor.\nEnglish oxygen\nEnglish -oxy\nEnglish alkoxy\nProto-Indo-European *kʷel-\nProto-Indo-European *kʷékʷlos\nAncient Greek κῠ́κλος (kŭ́klos)der.\nLate Latin cyclusbor.\nMiddle English cicle\nEnglish cycle\nProto-Indo-European *-id-\nProto-Indo-European *-yéti\nProto-Indo-European *-idyéti\nProto-Hellenic *-íďďō\nAncient Greek -ῐ́ζω (-ĭ́zō)bor.\nLate Latin -izōder.\nMiddle French -iserbor.\nMiddle English -isen\nEnglish -ize\nEnglish cyclize\nProto-Indo-European *-tisder.\nProto-Italic *-tjō\nLatin -tiō\nLatin -ātiōlbor.\nOld French -ationbor.\nMiddle English -acioun\nEnglish -ation\nEnglish cyclization\nEnglish alkoxycyclization\nFrom alkoxy + cyclization.",
  "forms": [
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  "pos": "noun",
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        "English terms derived from the Proto-Indo-European root *h₂eḱ-",
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          "ref": "2015 June 10, Ruth Dorel, Antonio M. Echavarren, “Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates”, in The Journal of Organic Chemistry, volume 80, →DOI:",
          "text": "A transition state similar to TS 34 – 33 has been proposed in the reaction of cyclopropyl gold(I) carbenes generated by retro-Buchner reaction of 7-cyclopropyl 1,3,5-cycloheptatrienes. 79 Gold(I) complexes are able to catalyze the addition of amines, alcohols, or water to 1, n -enynes affording products of amino-, alkoxy-, or hydroxycyclization under much milder conditions than other metal catalysts. 26, 32, 33, 62, 80 − 82 These additions are stereospecific, as illustrated by the alkoxycyclization of diastereomeric enynes 1m and 1h, and proceed via opening of cyclopropyl gold(I) carbene intermediates 35 by attack of the nucleophile to the cyclopropane ring (Scheme 11 ).",
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      "glosses": [
        "A reaction in which the addition of an alkoxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
      ],
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        "(organic chemistry) A reaction in which the addition of an alkoxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
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        "chemistry",
        "natural-sciences",
        "organic-chemistry",
        "physical-sciences"
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  "word": "alkoxycyclization"
}