See alkoxycyclization in All languages combined, or Wiktionary
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data-lang=\"en\" data-title=\"alkoxycyclization\">\nFrom alkoxy + cyclization.",
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"etymology_text": "Etymology tree\nAkkadian 𒎎𒋆𒁉𒍣𒁕 (guḫlum)bor.\nAramaic כוחלא (kuḥlā)bor.\nArabic كُحْل (kuḥl)\nAndalusian Arabic اَلْكُحُول (al-kuḥūl)bor.\nMedieval Latin alcoholder.\nMiddle English alcofol\nEnglish alcohol\nEnglish alk-\nProto-Indo-European *h₂eḱ-der.?\nAncient Greek ὀξύς (oxús)\nProto-Indo-European *ǵenh₁-\nProto-Indo-European *-os\nProto-Indo-European *ǵénh₁os\nProto-Hellenic *génos\nAncient Greek γένος (génos)\nFrench oxygènebor.\nEnglish oxygen\nEnglish -oxy\nEnglish alkoxy\nProto-Indo-European *kʷel-\nProto-Indo-European *kʷékʷlos\nAncient Greek κῠ́κλος (kŭ́klos)der.\nLate Latin cyclusbor.\nMiddle English cicle\nEnglish cycle\nProto-Indo-European *-id-\nProto-Indo-European *-yéti\nProto-Indo-European *-idyéti\nProto-Hellenic *-íďďō\nAncient Greek -ῐ́ζω (-ĭ́zō)bor.\nLate Latin -izōder.\nMiddle French -iserbor.\nMiddle English -isen\nEnglish -ize\nEnglish cyclize\nProto-Indo-European *-tis\nProto-Indo-European *-Hō\nProto-Indo-European *-tiHō\nProto-Italic *-tiō\nLatin -tiō\nLatin -ātiōlbor.\nOld French -ationbor.\nMiddle English -acioun\nEnglish -ation\nEnglish cyclization\nEnglish alkoxycyclization\nFrom alkoxy + cyclization.",
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"ref": "2015 June 10, Ruth Dorel, Antonio M. Echavarren, “Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates”, in The Journal of Organic Chemistry, volume 80, →DOI:",
"text": "A transition state similar to TS 34 – 33 has been proposed in the reaction of cyclopropyl gold(I) carbenes generated by retro-Buchner reaction of 7-cyclopropyl 1,3,5-cycloheptatrienes. 79 Gold(I) complexes are able to catalyze the addition of amines, alcohols, or water to 1, n -enynes affording products of amino-, alkoxy-, or hydroxycyclization under much milder conditions than other metal catalysts. 26, 32, 33, 62, 80 − 82 These additions are stereospecific, as illustrated by the alkoxycyclization of diastereomeric enynes 1m and 1h, and proceed via opening of cyclopropyl gold(I) carbene intermediates 35 by attack of the nucleophile to the cyclopropane ring (Scheme 11 ).",
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"glosses": [
"A reaction in which the addition of an alkoxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
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\"keyword\" : \"bor\" }, { \"terms\" : [ { \"id\" : \"root\", \"children\" : [ ], \"status\" : \"redlink\", \"lang_name\" : \"Arabic\", \"term\" : \"ك ح ل\", \"lang\" : \"ar\" } ], \"keyword\" : \"root\", \"is_invisible\" : \"all\" } ], \"lang_name\" : \"Arabic\", \"term\" : \"كُحْل\", \"status\" : \"ok\", \"lang\" : \"ar\" } ], \"keyword_label\" : \"Inherited from\", \"keyword\" : \"inherited\" } ], \"lang_name\" : \"Andalusian Arabic\", \"term\" : \"كُحُول\", \"status\" : \"inline\", \"lang\" : \"xaa\" } ], \"keyword\" : \"bor\" } ], \"lang_name\" : \"Medieval Latin\", \"term\" : \"alcohol\", \"status\" : \"ok\", \"lang\" : \"la-med\" } ], \"keyword\" : \"derived\" } ], \"status\" : \"inline\", \"lang_name\" : \"Middle English\", \"term\" : \"alcofol\", \"lang\" : \"enm\" } ], \"keyword_label\" : \"Inherited from\", \"keyword\" : \"inherited\" } ], \"lang_name\" : \"English\", \"term\" : \"alcohol\", \"status\" : \"ok\", \"lang\" : \"en\" } ], \"keyword_label\" : \"From\", \"keyword\" : \"from\" } ], \"lang_name\" : \"English\", \"term\" : \"alk-\", \"status\" : \"ok\", \"lang\" : \"en\" }, { \"children\" : [ { \"terms\" : [ { \"children\" : [ { \"keyword_abbrev\" : \"bor.\", \"keyword_label\" : \"Borrowed from\", \"terms\" : [ { \"id\" : \"oxygen\", \"children\" : [ { \"terms\" : [ { \"id\" : \"sharp\", \"children\" : [ { \"keyword_abbrev\" : \"der.\", \"keyword_label\" : \"Derived from\", \"terms\" : [ { \"is_uncertain\" : true, \"id\" : \"sharp\", \"children\" : [ ], \"status\" : \"ok\", \"lang_name\" : \"Proto-Indo-European\", \"term\" : \"*h₂eḱ-\", \"lang\" : \"ine-pro\" } ], \"keyword\" : \"derived\" } ], \"status\" : \"ok\", \"lang_name\" : \"Ancient Greek\", \"term\" : \"ὀξύς\", \"lang\" : \"grc\" }, { \"id\" : \"race\", \"children\" : [ { \"terms\" : [ { \"id\" : \"family\", \"children\" : [ { \"terms\" : [ { \"id\" : \"race\", \"children\" : [ { \"terms\" : [ { \"children\" : [ ], \"lang_name\" : \"Proto-Indo-European\", \"term\" : \"*ǵenh₁-\", 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data-lang=\"en\" data-title=\"alkoxycyclization\">\nFrom alkoxy + cyclization.",
"name": "etymon"
}
],
"etymology_text": "Etymology tree\nAkkadian 𒎎𒋆𒁉𒍣𒁕 (guḫlum)bor.\nAramaic כוחלא (kuḥlā)bor.\nArabic كُحْل (kuḥl)\nAndalusian Arabic اَلْكُحُول (al-kuḥūl)bor.\nMedieval Latin alcoholder.\nMiddle English alcofol\nEnglish alcohol\nEnglish alk-\nProto-Indo-European *h₂eḱ-der.?\nAncient Greek ὀξύς (oxús)\nProto-Indo-European *ǵenh₁-\nProto-Indo-European *-os\nProto-Indo-European *ǵénh₁os\nProto-Hellenic *génos\nAncient Greek γένος (génos)\nFrench oxygènebor.\nEnglish oxygen\nEnglish -oxy\nEnglish alkoxy\nProto-Indo-European *kʷel-\nProto-Indo-European *kʷékʷlos\nAncient Greek κῠ́κλος (kŭ́klos)der.\nLate Latin cyclusbor.\nMiddle English cicle\nEnglish cycle\nProto-Indo-European *-id-\nProto-Indo-European *-yéti\nProto-Indo-European *-idyéti\nProto-Hellenic *-íďďō\nAncient Greek -ῐ́ζω (-ĭ́zō)bor.\nLate Latin -izōder.\nMiddle French -iserbor.\nMiddle English -isen\nEnglish -ize\nEnglish cyclize\nProto-Indo-European *-tis\nProto-Indo-European *-Hō\nProto-Indo-European *-tiHō\nProto-Italic *-tiō\nLatin -tiō\nLatin -ātiōlbor.\nOld French -ationbor.\nMiddle English -acioun\nEnglish -ation\nEnglish cyclization\nEnglish alkoxycyclization\nFrom alkoxy + cyclization.",
"forms": [
{
"form": "alkoxycyclizations",
"tags": [
"plural"
]
}
],
"head_templates": [
{
"args": {},
"expansion": "alkoxycyclization (plural alkoxycyclizations)",
"name": "en-noun"
}
],
"lang": "English",
"lang_code": "en",
"pos": "noun",
"senses": [
{
"categories": [
"English compound terms",
"English countable nouns",
"English entries with etymology texts",
"English entries with etymology trees",
"English entries with incorrect language header",
"English lemmas",
"English nouns",
"English terms derived from the Arabic root ك ح ل",
"English terms derived from the Proto-Indo-European root *h₂eḱ-",
"English terms derived from the Proto-Indo-European root *kʷelh₁-",
"English terms derived from the Proto-Indo-European root *ǵenh₁-",
"English terms with quotations",
"Pages using etymon with no ID",
"Pages with 1 entry",
"Pages with entries",
"Pages with etymology trees",
"en:Chemical reactions",
"en:Organic chemistry"
],
"examples": [
{
"bold_text_offsets": [
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486,
503
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],
"ref": "2015 June 10, Ruth Dorel, Antonio M. Echavarren, “Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates”, in The Journal of Organic Chemistry, volume 80, →DOI:",
"text": "A transition state similar to TS 34 – 33 has been proposed in the reaction of cyclopropyl gold(I) carbenes generated by retro-Buchner reaction of 7-cyclopropyl 1,3,5-cycloheptatrienes. 79 Gold(I) complexes are able to catalyze the addition of amines, alcohols, or water to 1, n -enynes affording products of amino-, alkoxy-, or hydroxycyclization under much milder conditions than other metal catalysts. 26, 32, 33, 62, 80 − 82 These additions are stereospecific, as illustrated by the alkoxycyclization of diastereomeric enynes 1m and 1h, and proceed via opening of cyclopropyl gold(I) carbene intermediates 35 by attack of the nucleophile to the cyclopropane ring (Scheme 11 ).",
"type": "quotation"
}
],
"glosses": [
"A reaction in which the addition of an alkoxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
],
"links": [
[
"organic chemistry",
"organic chemistry"
],
[
"reaction",
"reaction"
],
[
"alkoxy",
"alkoxy"
],
[
"double",
"double bond"
],
[
"triple bond",
"triple bond"
],
[
"cyclization",
"cyclization"
]
],
"raw_glosses": [
"(organic chemistry) A reaction in which the addition of an alkoxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
],
"topics": [
"chemistry",
"natural-sciences",
"organic-chemistry",
"physical-sciences"
]
}
],
"word": "alkoxycyclization"
}
Download raw JSONL data for alkoxycyclization meaning in English (14.8kB)
This page is a part of the kaikki.org machine-readable English dictionary. This dictionary is based on structured data extracted on 2026-06-07 from the enwiktionary dump dated 2026-06-01 using wiktextract (e79dea5 and 7f4db16). The data shown on this site has been post-processed and various details (e.g., extra categories) removed, some information disambiguated, and additional data merged from other sources. See the raw data download page for the unprocessed wiktextract data.
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