"Curtius rearrangement" meaning in English

See Curtius rearrangement in All languages combined, or Wiktionary

Noun

Forms: Curtius rearrangements [plural]
Etymology: Introduced by Theodor Curtius in 1885. Head templates: {{en-noun}} Curtius rearrangement (plural Curtius rearrangements)
  1. (organic chemistry, physical chemistry) The thermal decomposition of an acyl azide to an isocyanate with loss of nitrogen gas. The isocyanate then undergoes attack by a variety of nucleophiles such as water, alcohols and amines, to yield a primary amine, carbamate or urea derivative respectively. Tags: physical Categories (topical): Chemical reactions, Organic chemistry, Physical chemistry Synonyms: Curtius degradation, Curtius reaction Derived forms: photo-Curtius rearrangement

Inflected forms

{
  "etymology_text": "Introduced by Theodor Curtius in 1885.",
  "forms": [
    {
      "form": "Curtius rearrangements",
      "tags": [
        "plural"
      ]
    }
  ],
  "head_templates": [
    {
      "args": {},
      "expansion": "Curtius rearrangement (plural Curtius rearrangements)",
      "name": "en-noun"
    }
  ],
  "lang": "English",
  "lang_code": "en",
  "pos": "noun",
  "senses": [
    {
      "categories": [
        {
          "kind": "other",
          "name": "English entries with incorrect language header",
          "parents": [
            "Entries with incorrect language header",
            "Entry maintenance"
          ],
          "source": "w"
        },
        {
          "kind": "other",
          "name": "Pages with 1 entry",
          "parents": [],
          "source": "w"
        },
        {
          "kind": "other",
          "name": "Pages with entries",
          "parents": [],
          "source": "w"
        },
        {
          "kind": "topical",
          "langcode": "en",
          "name": "Chemical reactions",
          "orig": "en:Chemical reactions",
          "parents": [
            "Chemistry",
            "Sciences",
            "All topics",
            "Fundamental"
          ],
          "source": "w"
        },
        {
          "kind": "topical",
          "langcode": "en",
          "name": "Organic chemistry",
          "orig": "en:Organic chemistry",
          "parents": [
            "Chemistry",
            "Sciences",
            "All topics",
            "Fundamental"
          ],
          "source": "w"
        },
        {
          "kind": "topical",
          "langcode": "en",
          "name": "Physical chemistry",
          "orig": "en:Physical chemistry",
          "parents": [
            "Chemistry",
            "Physics",
            "Sciences",
            "All topics",
            "Fundamental"
          ],
          "source": "w"
        }
      ],
      "derived": [
        {
          "word": "photo-Curtius rearrangement"
        }
      ],
      "glosses": [
        "The thermal decomposition of an acyl azide to an isocyanate with loss of nitrogen gas. The isocyanate then undergoes attack by a variety of nucleophiles such as water, alcohols and amines, to yield a primary amine, carbamate or urea derivative respectively."
      ],
      "id": "en-Curtius_rearrangement-en-noun-uPxbD1R~",
      "links": [
        [
          "organic chemistry",
          "organic chemistry"
        ],
        [
          "physical chemistry",
          "physical chemistry"
        ],
        [
          "thermal",
          "thermal"
        ],
        [
          "decomposition",
          "decomposition"
        ],
        [
          "acyl",
          "acyl"
        ],
        [
          "azide",
          "azide"
        ],
        [
          "isocyanate",
          "isocyanate"
        ],
        [
          "nitrogen",
          "nitrogen"
        ],
        [
          "gas",
          "gas"
        ]
      ],
      "raw_glosses": [
        "(organic chemistry, physical chemistry) The thermal decomposition of an acyl azide to an isocyanate with loss of nitrogen gas. The isocyanate then undergoes attack by a variety of nucleophiles such as water, alcohols and amines, to yield a primary amine, carbamate or urea derivative respectively."
      ],
      "synonyms": [
        {
          "word": "Curtius degradation"
        },
        {
          "word": "Curtius reaction"
        }
      ],
      "tags": [
        "physical"
      ],
      "topics": [
        "chemistry",
        "natural-sciences",
        "organic-chemistry",
        "physical-sciences"
      ]
    }
  ],
  "word": "Curtius rearrangement"
}
{
  "derived": [
    {
      "word": "photo-Curtius rearrangement"
    }
  ],
  "etymology_text": "Introduced by Theodor Curtius in 1885.",
  "forms": [
    {
      "form": "Curtius rearrangements",
      "tags": [
        "plural"
      ]
    }
  ],
  "head_templates": [
    {
      "args": {},
      "expansion": "Curtius rearrangement (plural Curtius rearrangements)",
      "name": "en-noun"
    }
  ],
  "lang": "English",
  "lang_code": "en",
  "pos": "noun",
  "senses": [
    {
      "categories": [
        "English countable nouns",
        "English entries with incorrect language header",
        "English eponyms",
        "English lemmas",
        "English multiword terms",
        "English nouns",
        "Pages with 1 entry",
        "Pages with entries",
        "en:Chemical reactions",
        "en:Organic chemistry",
        "en:Physical chemistry"
      ],
      "glosses": [
        "The thermal decomposition of an acyl azide to an isocyanate with loss of nitrogen gas. The isocyanate then undergoes attack by a variety of nucleophiles such as water, alcohols and amines, to yield a primary amine, carbamate or urea derivative respectively."
      ],
      "links": [
        [
          "organic chemistry",
          "organic chemistry"
        ],
        [
          "physical chemistry",
          "physical chemistry"
        ],
        [
          "thermal",
          "thermal"
        ],
        [
          "decomposition",
          "decomposition"
        ],
        [
          "acyl",
          "acyl"
        ],
        [
          "azide",
          "azide"
        ],
        [
          "isocyanate",
          "isocyanate"
        ],
        [
          "nitrogen",
          "nitrogen"
        ],
        [
          "gas",
          "gas"
        ]
      ],
      "raw_glosses": [
        "(organic chemistry, physical chemistry) The thermal decomposition of an acyl azide to an isocyanate with loss of nitrogen gas. The isocyanate then undergoes attack by a variety of nucleophiles such as water, alcohols and amines, to yield a primary amine, carbamate or urea derivative respectively."
      ],
      "synonyms": [
        {
          "word": "Curtius degradation"
        },
        {
          "word": "Curtius reaction"
        }
      ],
      "tags": [
        "physical"
      ],
      "topics": [
        "chemistry",
        "natural-sciences",
        "organic-chemistry",
        "physical-sciences"
      ]
    }
  ],
  "word": "Curtius rearrangement"
}

Download raw JSONL data for Curtius rearrangement meaning in English (1.7kB)


This page is a part of the kaikki.org machine-readable English dictionary. This dictionary is based on structured data extracted on 2024-11-06 from the enwiktionary dump dated 2024-10-02 using wiktextract (fbeafe8 and 7f03c9b). The data shown on this site has been post-processed and various details (e.g., extra categories) removed, some information disambiguated, and additional data merged from other sources. See the raw data download page for the unprocessed wiktextract data.

If you use this data in academic research, please cite Tatu Ylonen: Wiktextract: Wiktionary as Machine-Readable Structured Data, Proceedings of the 13th Conference on Language Resources and Evaluation (LREC), pp. 1317-1325, Marseille, 20-25 June 2022. Linking to the relevant page(s) under https://kaikki.org would also be greatly appreciated.