"hydroxycyclization" meaning in All languages combined

{
  "etymology_templates": [
    {
      "args": {
        "1": "en",
        "2": "hydroxy",
        "3": "cyclization"
      },
      "expansion": "hydroxy + cyclization",
      "name": "compound"
    }
  ],
  "etymology_text": "From hydroxy + cyclization.",
  "forms": [
    {
      "form": "hydroxycyclizations",
      "tags": [
        "plural"
      ]
    }
  ],
  "head_templates": [
    {
      "args": {},
      "expansion": "hydroxycyclization (plural hydroxycyclizations)",
      "name": "en-noun"
    }
  ],
  "lang": "English",
  "lang_code": "en",
  "pos": "noun",
  "senses": [
    {
      "categories": [
        {
          "kind": "other",
          "name": "English entries with incorrect language header",
          "parents": [
            "Entries with incorrect language header",
            "Entry maintenance"
          ],
          "source": "w"
        },
        {
          "kind": "other",
          "name": "Pages with 1 entry",
          "parents": [],
          "source": "w"
        },
        {
          "kind": "topical",
          "langcode": "en",
          "name": "Organic chemistry",
          "orig": "en:Organic chemistry",
          "parents": [
            "Chemistry",
            "Sciences",
            "All topics",
            "Fundamental"
          ],
          "source": "w"
        }
      ],
      "examples": [
        {
          "ref": "2015 June 10, Ruth Dorel, Antonio M. Echavarren, “Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates”, in The Journal of Organic Chemistry, volume 80, →DOI:",
          "text": "A transition state similar to TS 34 – 33 has been proposed in the reaction of cyclopropyl gold(I) carbenes generated by retro-Buchner reaction of 7-cyclopropyl 1,3,5-cycloheptatrienes. 79 Gold(I) complexes are able to catalyze the addition of amines, alcohols, or water to 1, n -enynes affording products of amino-, alkoxy-, or hydroxycyclization under much milder conditions than other metal catalysts. 26, 32, 33, 62, 80 − 82 These additions are stereospecific, as illustrated by the alkoxycyclization of diastereomeric enynes 1m and 1h, and proceed via opening of cyclopropyl gold(I) carbene intermediates 35 by attack of the nucleophile to the cyclopropane ring (Scheme 11 ).",
          "type": "quote"
        }
      ],
      "glosses": [
        "A reaction in which the addition of a hydroxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
      ],
      "id": "en-hydroxycyclization-en-noun-rryi4ykZ",
      "links": [
        [
          "organic chemistry",
          "organic chemistry"
        ],
        [
          "reaction",
          "reaction"
        ],
        [
          "hydroxy",
          "hydroxy"
        ],
        [
          "double",
          "double bond"
        ],
        [
          "triple bond",
          "triple bond"
        ],
        [
          "cyclization",
          "cyclization"
        ]
      ],
      "raw_glosses": [
        "(organic chemistry) A reaction in which the addition of a hydroxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
      ],
      "topics": [
        "chemistry",
        "natural-sciences",
        "organic-chemistry",
        "physical-sciences"
      ]
    }
  ],
  "word": "hydroxycyclization"
}

{
  "etymology_templates": [
    {
      "args": {
        "1": "en",
        "2": "hydroxy",
        "3": "cyclization"
      },
      "expansion": "hydroxy + cyclization",
      "name": "compound"
    }
  ],
  "etymology_text": "From hydroxy + cyclization.",
  "forms": [
    {
      "form": "hydroxycyclizations",
      "tags": [
        "plural"
      ]
    }
  ],
  "head_templates": [
    {
      "args": {},
      "expansion": "hydroxycyclization (plural hydroxycyclizations)",
      "name": "en-noun"
    }
  ],
  "lang": "English",
  "lang_code": "en",
  "pos": "noun",
  "senses": [
    {
      "categories": [
        "English compound terms",
        "English countable nouns",
        "English entries with incorrect language header",
        "English lemmas",
        "English nouns",
        "English terms with quotations",
        "Pages with 1 entry",
        "en:Organic chemistry"
      ],
      "examples": [
        {
          "ref": "2015 June 10, Ruth Dorel, Antonio M. Echavarren, “Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates”, in The Journal of Organic Chemistry, volume 80, →DOI:",
          "text": "A transition state similar to TS 34 – 33 has been proposed in the reaction of cyclopropyl gold(I) carbenes generated by retro-Buchner reaction of 7-cyclopropyl 1,3,5-cycloheptatrienes. 79 Gold(I) complexes are able to catalyze the addition of amines, alcohols, or water to 1, n -enynes affording products of amino-, alkoxy-, or hydroxycyclization under much milder conditions than other metal catalysts. 26, 32, 33, 62, 80 − 82 These additions are stereospecific, as illustrated by the alkoxycyclization of diastereomeric enynes 1m and 1h, and proceed via opening of cyclopropyl gold(I) carbene intermediates 35 by attack of the nucleophile to the cyclopropane ring (Scheme 11 ).",
          "type": "quote"
        }
      ],
      "glosses": [
        "A reaction in which the addition of a hydroxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
      ],
      "links": [
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          "organic chemistry",
          "organic chemistry"
        ],
        [
          "reaction",
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        ],
        [
          "hydroxy",
          "hydroxy"
        ],
        [
          "double",
          "double bond"
        ],
        [
          "triple bond",
          "triple bond"
        ],
        [
          "cyclization",
          "cyclization"
        ]
      ],
      "raw_glosses": [
        "(organic chemistry) A reaction in which the addition of a hydroxy group to one carbon atom of a double or triple bond is accompanied by cyclization"
      ],
      "topics": [
        "chemistry",
        "natural-sciences",
        "organic-chemistry",
        "physical-sciences"
      ]
    }
  ],
  "word": "hydroxycyclization"
}